76. Joaquin Phoenix and Liv Tyler

Liv Tyler is the famous daughter of rockstar Steven Tyler. Though she did not follow her father’s footsteps in the music industry, she did make a name for herself in Hollywood. She was once married to Royston Langdon, but you probably remember her relationship with distinguished actor Joaquin Phoenix. Tyler is famous worldwide for her role in the Lord of the Rings franchise and movies such as Armageddon, Reign Over Me, and Inventing the Abbotts, where she co-starred with Phoenix.

They kept their relationship a secret for a time and even kept it hidden from their coworkers. In an interview the actress did with The Morning Call, she confessed to falling in love with him the moment she met him. Their relationship lasted for three years until they decided to mutually part ways. They even have the fortunate insurance of being good friends even after their break up.